Published January 15, 1986
| Version v1
Journal article
Structure of barium dipotassium hexanitrocobaltate(II): A redetermination
Creators
- 1. Sydney Univ. (Australia). Dept. of Inorganic Chemistry
Description
BaK2[Co(NO2)6], Msub(r)=550.5, cubic, Fm3, a=10.653 (2) A, V=1209.0 A3, Z=4, Dsub(x)=3.024 g cm-3, Mo Kα, lambda=0.71069 A, μ=53.45 cm-1, F(000)=1036, T=294 K, final R=0.027 for 323 reflections. The [Co(NO2)6]4- anion has m3 (Tsub(h)) symmetry. The Co-N distance is 2.010 (3) A, which is only 0.06 A longer than in an analogous Cosup(I)II complex. The thermal ellipsoid of the N atom reveals no anisotropy, in contrast with other structures containing the same complex anion. (orig.)
Additional details
Publishing Information
- Journal Title
- Acta Crystallogr., Sect. C: Cryst. Struct. Commun.
- Journal Volume
- 42
- Journal Issue
- 1
- Series
- Acta Crystallogr., Sect. C: Cryst. Struct. Commun.
- Journal Page Range
- 11-13
- ISSN
- 0108-2701
- CODEN
- ACSCE
INIS
- Country of Publication
- Denmark
- Country of Input or Organization
- Denmark
- INIS RN
- 17043162
- Subject category
- S36: MATERIALS SCIENCE;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- BARIUM OXIDES; BOND ANGLE; COBALT OXIDES; CRYSTAL STRUCTURE; CUBIC LATTICES; EXPERIMENTAL DATA; INTERATOMIC DISTANCES; LATTICE PARAMETERS; MEDIUM TEMPERATURE; NITRO COMPOUNDS; POTASSIUM OXIDES; X-RAY DIFFRACTION
- Descriptors DEC
- ALKALI METAL COMPOUNDS; ALKALINE EARTH METAL COMPOUNDS; BARIUM COMPOUNDS; CHALCOGENIDES; COBALT COMPOUNDS; COHERENT SCATTERING; CRYSTAL LATTICES; DATA; DIFFRACTION; DISTANCE; INFORMATION; NUMERICAL DATA; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; POTASSIUM COMPOUNDS; SCATTERING; TRANSITION ELEMENT COMPOUNDS