Published June 1988
| Version v1
Journal article
Organic chemistry of dinuclear metal centres. Part 11. Combination of allene with dimethyl acetylenedicarboxylate at a dimolybdenum centre: X-ray structures of [Mo2(μC2(CO2Me)2) (μ-C(CH2)2C(O) C(CO2Me) C(CO2Me)) (η-C5H5)2] and [Mo2(μ-C2(CO2Me)2)-(μ-C(CH2)2 C(CO2Me) C(CO2Me)) (η-C5H5)2]
- 1. Bristol Univ. (UK). Dept. of Biochemistry
Description
Synthesis of the complexes is reported. The structures of the complexes have been established by X-ray diffraction, showing that each contains a dimolybdenum unit with metal-metal bond order two, bridged transversely by a molecule of the alkyne. 25 refs
Additional details
Publishing Information
- Journal Title
- New Journal of Chemistry
- Journal Volume
- 12
- Journal Issue
- 6-7
- Series
- New J. Chem.
- Journal Page Range
- 581-587
- ISSN
- 0398-9836
- CODEN
- NJCHD
INIS
- Country of Publication
- France
- Country of Input or Organization
- France
- INIS RN
- 20014806
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CHEMICAL PREPARATION; CRYSTAL STRUCTURE; MOLECULAR STRUCTURE; MOLYBDENUM COMPLEXES
- Descriptors DEC
- COMPLEXES; SYNTHESIS; TRANSITION ELEMENT COMPLEXES