Photocatalytic degradation of pesticides by nanofibrous membranes fabricated by colloid-electrospinning

Photocatalytic degradation of organic pollutants is a promising way to clean wastewater. Herein, we develop and compare two processes for fabricating nanofibrous membranes with photocatalytic properties. Hybrid nanofibers are produced by colloid-electrospinning and composed of metal oxide nanoparticles on sintered SiO₂ nanoparticles. The latter serves as support for the photocatalyst and preserves the structural integrity of nanofibers. Adsorption of metal salts on crosslinked polymer/SiO₂ fibers followed by calcination allows for the obtention of fibers with large amounts of metal oxide. Nanofibrous membranes with supported ZnO, In₂O₃, or mixture of both, display photocatalytic activity upon UV irradiation. The membranes can degrade a dye and an organophosphate pesticide more effectively than membranes directly fabricated from the calcination of metal oxides. (paper)