Published August 1994 | Version v1
Journal article Metadata-only

Direct 14,15N NMR observation of inert platinum-metal nitrato complexes in an aqueous solution

Creators

  • 1. AN SSSR, Novosibirsk (Russian Federation). Inst. Neorganicheskoj Khimii
  • 2. AN SSSR, Novosibirsk (Russian Federation). Inst. Kataliza

Description

Conditions of stabilization and observation by the NMR method of Rn(3), Ru(2) and Pd(2) nitrate complexes in aqueous solutions have been studied. It is shown that in concentrated nitric acid there exist nitrate complexes of platinum metals, which are revealed by the lines in 14,15N, 17O NMR spectra with NO3- lifetime in the complex > 3 ms for Ru(2) and Pd(2). 9 refs.; 1 fig.; 1 tab

Additional details

Additional titles

Original title (Russian)
Прямое наблюдение инертных нитратокомплексов платиновых металлов методом YaMR

Publishing Information

Journal Title
Koordinatsionnaya Khimiya
Journal Volume
20
Journal Issue
8-9
Journal Page Range
p. 613-615.
ISSN
0132-344X
CODEN
KOKHDC

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
27010053
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AQUEOUS SOLUTIONS; CONCENTRATION RATIO; LIFETIME; NITRATES; NITRIC ACID; NITROGEN 14; NITROGEN 15; NMR SPECTRA; OXYGEN 17; RUTHENIUM COMPLEXES
Descriptors DEC
COMPLEXES; DISPERSIONS; EVEN-ODD NUCLEI; HOMOGENEOUS MIXTURES; HYDROGEN COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; ISOTOPES; LIGHT NUCLEI; MIXTURES; NITROGEN COMPOUNDS; NITROGEN ISOTOPES; NUCLEI; ODD-EVEN NUCLEI; ODD-ODD NUCLEI; OXYGEN COMPOUNDS; OXYGEN ISOTOPES; SOLUTIONS; SPECTRA; STABLE ISOTOPES; TRANSITION ELEMENT COMPLEXES