Published 1989 | Version v1
Journal article

Radioiodination via vinylstannylated alkylating agents

  • 1. Johns Hopkins Univ., Baltimore, MD (USA). Dept. of Radiology
  • 2. Johns Hopkins Univ., Baltimore, MD (USA). Dept. of Environmental Health Sciences

Description

ρ-Toluenesulfonate esters of (E)- and (Z)-3-(tri-n-butylstannyl)-2-propen-1-o1 readily react with nucleophiles to give vinylstannanes which are substrates for rapid, efficient and stereospecific radioiododestannylation at the no-carrier-added level. This general approach is illustrated by syntheses of iodinated spiperone analogs for studies of dopamine D2 receptors. (author)

Additional details

Publishing Information

Journal Title
Tetrahedron Letters
Journal Volume
30
Journal Issue
28
Series
Tetrahedron Lett.
Journal Page Range
3613-3616
ISSN
0040-4039
CODEN
TELEA

Optional Information

Contract/Grant/Project number
Grant CA32845; CA09199