Complexing of molybdenum (5 and 6) oxychlorides with diphenyldithiophosphinic acid
Creators
- 1. AN SSSR, Moscow. Inst. Obshchej i Neorganicheskoj Khimii
Description
The method has been used to identify MoO3+ complexes with Ph2PSS- ligand in non-polar and polar organic solvents MoOCl3 complexing with Ph2PSSH is shown to be followed by step substitution of phosphinate groUps for chlorine ions. MoOClsub(3-x)(SPSPhsub(2))sub(x) complexes (where x=1-3) are revealed oin the solutions. Phosphinates of MoO(SPSPh2)3, MoO(OC2H5)x(SPSPh2)2, MoOCl(SPSPh2)3, MoO(OC2H5)(SPSPh2)3 and MoO2(SPSPh2)2 respectively are extacted as a result of MoOCl3, MoOCl4 and MoO2Cl2 reactions with Ph2PSSH. Dithiophosphinates with coordination number of Mo(5) equal to 5 of MoOCl2(SPSPh2) and [MoOS2PPh2]2 (μ-S)2xC6H6 composition are also synthesized. Structure of the prepared complexes is determined by means of IR specta, data on magnetic susceptibility and molecular masses
Additional details
Additional titles
- Original title (Russian)
- Комплексообразование оксохлоридов молибдена (5) и (6) с дифенилдитиофосфиновой кислотой
Publishing Information
- Journal Title
- Koord. Khim.
- Journal Volume
- 9
- Journal Issue
- 2
- Series
- Koord. Khim.
- Journal Page Range
- 221-226
- ISSN
- 0132-344X
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- USSR
- INIS RN
- 15012415
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CHEMICAL REACTION YIELD; ELECTRON SPIN RESONANCE; INFRARED SPECTRA; MAGNETIC SUSCEPTIBILITY; MOLECULAR STRUCTURE; MOLYBDENUM COMPLEXES; ORGANIC PHOSPHORUS COMPOUNDS; ORGANIC SULFUR COMPOUNDS; OXYCHLORIDES
- Descriptors DEC
- CHLORINE COMPOUNDS; COMPLEXES; HALOGEN COMPOUNDS; MAGNETIC PROPERTIES; MAGNETIC RESONANCE; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; RESONANCE; SPECTRA; SYNTHESIS; TRANSITION ELEMENT COMPLEXES