Published February 1986 | Version v1
Journal article

Moessbauer study of isothermal crystallization kinetics of the amorphous iron III fluoride FeF3,0.4HF

  • 1. Laboratoire Moessbauer, Le Mans, France
  • 2. Laboratoire des Fluorures, Faculte des Sciences, Le Mans, France

Description

The amorphous fluoride FeF3,xHF (0.4 <approx. x <approx. 1) synthetized by a soft chemistry reaction, crystallizes to R-FeF3. Crystallization was followed as a function of time at several constant temperatures by Moessbauer spectroscopy. The evolution of R-FeF3 rate is in good agreement with a Johnson-Mehl-Avrami transformation equation: the crystallization proceeds like a first-order reaction with an activation energy of approx. 2 eV. (Auth.)

Additional details

Publishing Information

Journal Title
Hyperfine Interact.
Journal Volume
27
Journal Issue
1-4
Series
Hyperfine Interact.
Journal Page Range
317-320
ISSN
0304-3843
CODEN
HYIND

Conference

Title
International conference on the applications of the Moessbauer effect.
Dates
16-20 Sep 1985.
Place
Leuven (Belgium).

INIS

Country of Publication
Netherlands
Country of Input or Organization
Switzerland
INIS RN
17045952
Subject category
S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
Resource subtype / Literary indicator
Conference
Descriptors DEI
AMORPHOUS STATE; ANNEALING; CRYSTALLIZATION; IRON FLUORIDES; MOESSBAUER EFFECT
Descriptors DEC
FLUORIDES; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; HEAT TREATMENTS; IRON COMPOUNDS; PHASE TRANSFORMATIONS; TRANSITION ELEMENT COMPOUNDS