Published September 1975 | Version v1
Journal article

Investigation into chemism of multivalent element ions reactions with organic reagents

  • 1. AN Ukrainskoj SSR, Odessa. Inst. Obshchej i Neorganicheskoj Khimii
  • 2. AN Ukrainskoj SSR, Kiev. Inst. Obshchej i Neorganicheskoj Khimii

Description

Spectrophotometric invectigations have been made in to the interaction of indium with alizarin red S (alizarin-3-sulphonic acid) when extracting it with chloroform. The complex is extracted as an ion association with diphenylguanidine, in which the ratio In:Aliz:DPG = 1:3:3. The central ion In3+ substitutes three protons in three particles of the ligand. The structure of the complex being extracted is discussed. Molar absorbancy index of the complex in the chloroform extract (2.8x104) is twice greater than in the aqueous solution. The effect of the pH value on the formation of the indium complexes extracted is studied

Additional details

Additional titles

Subtitle (English)
Comminication 32. Extractable indium complex with alizarin-3-sulfonic acid and diphenylguanidine
Original title (Russian)
Исследование химизма реакций ионов многовалентных элементов с органическими реагентами
Original subtitle (Russian)
Soobshchenie 32. Ehkstragiruemyj komplex indiya s alizarin-3-sulfokislotoj i difenilguanidinom.

Publishing Information

Journal Title
Zh. Anal. Khim.
Journal Volume
30
Journal Issue
9
Series
Zh. Anal. Khim.
Journal Page Range
1720-1723

Optional Information

Notes
For English translation see the journal J. Anal. Chem. USSR.