Published September 1975
| Version v1
Journal article
Investigation into chemism of multivalent element ions reactions with organic reagents
Creators
- 1. AN Ukrainskoj SSR, Odessa. Inst. Obshchej i Neorganicheskoj Khimii
- 2. AN Ukrainskoj SSR, Kiev. Inst. Obshchej i Neorganicheskoj Khimii
Description
Spectrophotometric invectigations have been made in to the interaction of indium with alizarin red S (alizarin-3-sulphonic acid) when extracting it with chloroform. The complex is extracted as an ion association with diphenylguanidine, in which the ratio In:Aliz:DPG = 1:3:3. The central ion In3+ substitutes three protons in three particles of the ligand. The structure of the complex being extracted is discussed. Molar absorbancy index of the complex in the chloroform extract (2.8x104) is twice greater than in the aqueous solution. The effect of the pH value on the formation of the indium complexes extracted is studied
Additional details
Additional titles
- Subtitle (English)
- Comminication 32. Extractable indium complex with alizarin-3-sulfonic acid and diphenylguanidine
- Original title (Russian)
- Исследование химизма реакций ионов многовалентных элементов с органическими реагентами
- Original subtitle (Russian)
- Soobshchenie 32. Ehkstragiruemyj komplex indiya s alizarin-3-sulfokislotoj i difenilguanidinom.
Publishing Information
- Journal Title
- Zh. Anal. Khim.
- Journal Volume
- 30
- Journal Issue
- 9
- Series
- Zh. Anal. Khim.
- Journal Page Range
- 1720-1723
INIS
- Country of Publication
- USSR
- Country of Input or Organization
- USSR
- INIS RN
- 7272291
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ANTHRAQUINONES; CHEMICAL REACTION KINETICS; CHEMICAL REACTIONS; CHLOROFORM; INDIUM COMPLEXES; INDIUM COMPOUNDS; MOLECULAR STRUCTURE; PH VALUE; SOLVENT EXTRACTION; SPECTROPHOTOMETRY; SULFONIC ACIDS
- Descriptors DEC
- AROMATICS; COMPLEXES; KINETICS; ORGANIC ACIDS; ORGANIC CHLORINE COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; ORGANIC SULFUR COMPOUNDS; QUINONES; REACTION KINETICS; SEPARATION PROCESSES
Optional Information
- Notes
- For English translation see the journal J. Anal. Chem. USSR.