Published October 2012 | Version v1
Journal article Metadata-only

Synthesis, Structure and Thermal Properties of Bifurazano[3,4-b:3',4'-f ]furoxano[3'',4''-d]oxacyclohetpatriene (BFFO)

Creators

  • 1. Xi'an Modern Chemistry Research Institute, Xi'an (China)
  • 2. Northwest Univ., Xi'an (China)

Description

A novel energetic compound, bifurazano[3,4-b:3',4'-f ]furoxano[3'',4''-d] oxacyclohetpatriene (BFFO), was synthesized through special etherification and its structure was determined by single crystal X-ray diffraction. The crystal of BFFO·H2O is monoclinic, space group P2(1)/c with crystal parameters of a = 9.324(4) A, b = 9.727(4) A, c = 10.391(4) A, β = 106.305(6) .deg., V = 904.5(6) A3, Z = 4, μ = 0.17 mm-1, F(000) = 512 and Dc = 1.866 g cm-3. Spectroscopic properties and thermal behaviors of BFFO were studied. BFFO presents good detonation properties

Additional details

Publishing Information

Journal Title
Bulletin of the Korean Chemical Society
Journal Volume
33
Journal Issue
10
Series
17 refs, 5 figs, 4 tabs
Journal Page Range
p. 3317-3320
ISSN
0253-2964

INIS

Country of Publication
Korea, Republic of
Country of Input or Organization
Korea, Republic of
INIS RN
45096373
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CRYSTALS; SYNTHESIS; THERMODYNAMIC PROPERTIES; X-RAY DIFFRACTION
Descriptors DEC
COHERENT SCATTERING; DIFFRACTION; PHYSICAL PROPERTIES; SCATTERING