Published July 1988 | Version v1
Journal article Metadata-only

Concentration oscillations of zinc tetra-4-tert-butylphthalocyanine in ethanol in pulsed radiolysis

Creators

  • 1. L.Ya. Karpov Scientific-Research Institute of Physical Chemistry (USSR)

Description

Deaerated solutions of monomeric zinc tetra-4-tert-butylphthalocyanine (ZnPC) in ethanol were studied by spectrophotometry directly during γ and pulsed microsecond radiolysis. It was shown that the ZnPC monoanion is formed on decomposition of the extracomplex of ZnPC with the hydroxyethyl radical and subsequent conversion of the monoanion into the starting ZnPC is accompanied by concentration oscillations. A model system of reactions is proposed which describes the experimental characteristics

Additional details

Publishing Information

Journal Title
High Energy Chemistry (English Translation)
Journal Volume
22
Journal Issue
1
Series
High Energy Chem. (Engl. Transl.).
Journal Page Range
17-20
ISSN
0018-1439
CODEN
HIECA

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
20083445
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Resource subtype / Literary indicator
Translation
Descriptors DEI
ANIONS; CHEMICAL REACTION KINETICS; ELECTRON BEAMS; EQUILIBRIUM; ETHANOL; GAMMA RADIATION; MATHEMATICAL MODELS; NUMERICAL SOLUTION; OPACITY; OSCILLATIONS; PHTHALOCYANINES; PULSED IRRADIATION; QUANTITY RATIO; RADIOLYSIS; SPECTROPHOTOMETRY; ZINC COMPLEXES
Descriptors DEC
ALCOHOLS; BEAMS; CHARGED PARTICLES; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; COMPLEXES; DECOMPOSITION; DYES; ELECTROMAGNETIC RADIATION; HETEROCYCLIC COMPOUNDS; HYDROXY COMPOUNDS; IONIZING RADIATIONS; IONS; IRRADIATION; KINETICS; LEPTON BEAMS; OPTICAL PROPERTIES; ORGANIC COMPOUNDS; PARTICLE BEAMS; PHYSICAL PROPERTIES; RADIATION EFFECTS; RADIATIONS; REACTION KINETICS

Optional Information

Notes
Translated from Khim. Vys. Energ.; 22: No. 1, 22-25(Jan-Feb 1988). Cover-to-cover translation of Khimiya Vysokikh Ehnergij (USSR).