Published 1978
| Version v1
Journal article
Pure rotational Raman spectrum of XeF2
Description
The pure rotational Raman spectrum of XeF2 has been recorded photographically with a reciprocal linear dispersion of 1.4 cm-1 mm-1 and analysed to yield the following values of the rotational constants and bond length: B0 = 0.113 27 +- 0.000 01 cm-1; 108D0 = 2.1 +- 0.2 cm-1; r0 = 197.91 +- 0.01 pm. These B0 and r0 values are much more precise than earlier infrared values. The B0 value does not overlap with the earlier infrared value and possible reasons for this discrepancy are discussed. (author)
Additional details
Identifiers
- DOI
- 10.1039/f29787401208;
Publishing Information
- Journal Title
- Journal of the Chemical Society, Faraday Transactions 2
- Journal Volume
- 74
- Journal Issue
- pt.7
- Series
- J. Chem. Soc. (London), Faraday Trans., II.
- Journal Page Range
- 1208
- ISSN
- 0300-9238
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- United Kingdom
- INIS RN
- 9412502
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- BOND LENGTHS; RAMAN SPECTRA; ROTATIONAL STATES; XENON FLUORIDES
- Descriptors DEC
- ENERGY LEVELS; EXCITED STATES; FLUORIDES; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; RARE GAS COMPOUNDS; SPECTRA; XENON COMPOUNDS
Optional Information
- Notes
- Updated automatically by Metadata and Full-Text Enrichment Agent