Parameterized atmospheric oxidation capacity and speciated OH reactivity over a suburban site in the North China Plain: A comparative study between summer and winter

Highlights: • The AOC was higher in summer, but the speciated OH reactivity was higher in winter • CO was the major reductant contributor to the AOC, and NOx dominated the OH reactivity • Among VOCs, alkenes and OVOCs were the dominant contributors to the AOC and OH reactivity • Aromatics and alkenes should be targeted first for O₃ mitigation • Traffic-related emissions and solvent usage were the main anthropogenic sources of the AOC, OH reactivity and O₃ formation The atmospheric oxidation capacity (AOC) and photochemical reactivity are of increasing concern owing to their roles in photochemical pollution. The AOC and OH reactivity were evaluated based on simultaneous measurements of volatile organic compounds (VOCs), trace gases and photolysis frequency during summer and winter campaigns at a suburban site in Xianghe. The AOC exhibited well-defined seasonal and diurnal patterns, with higher intensities during the summertime and daytime than during the wintertime and nighttime, respectively. The major reductants contributing to the AOC during the summertime were CO (41%) and alkenes (41%), whereas CO (40%) and oxygenated VOCs (OVOCs) (30%) dominated the AOC during the wintertime. The dominant oxidant contributor to the AOC during the daytime was OH (≥93%), while the contributions of O₃ and NO₃ (≥75%) to the AOC increased during the nighttime. High values during the wintertime and an increase at night were features of the speciated OH reactivity. Inorganic compounds (NO_x and CO) dominated the speciated OH reactivity (76% and 85% during the summer and winter campaigns, respectively). Among VOCs, the dominant contributors were alkenes (12%) and OVOCs (7%) during the summer and winter campaigns, respectively. The ratio of NO_x- and VOC-attributed OH reactivity indicated that O₃ formation occurred under a VOC-limited regime during the summertime and that aromatics had the largest potential to form O_3. Isoprene and m/p-xylene were the most important contributors to the AOC, OH reactivity and O₃-forming among VOCs during the summertime, biogenic sources and secondary formation and industrial production were the main sources of these species. During the wintertime, hexanal and ethylene were the key VOC species contributing to the AOC and OH reactivity, and solvent usage and traffic-related emissions were the main contributing sources. We recommend that priority measures for the control of VOC species and sources should be taken when suitable.