Published July 2005 | Version v1
Journal article

Investigation of quadrupole interactions in the CuO cation sites by means of the 57Fe3+ and 57mFe3+ Moessbauer probes

  • 1. National University of Uzbekistan, Tashkent (Uzbekistan)
  • 2. Tashkent Regional State of Pedagogical Institute, Angren (Uzbekistan)
  • 3. St. Petersburg State Polytechnical University, St. Petersburg (Russian Federation)

Description

Moessbauer emission spectroscopy of the 57Co (57m Fe) isotope has shown that the impurity iron atoms appearing at the CuO-lattice cation sites after the decay of 57Co2+ are donors and can stabilize in two charge states, 57mFe3+ and 57mFe2+, and that the population ratio of these states depends on the Fermi level, whose position is governed by native CuO-lattice defects. A satisfactory agreement between the calculated and experimental values of the quadrupole splitting in Moessbauer spectra has been obtained for the 57mFe3+centers. (author)

Additional details

Publishing Information

Journal Title
Uzbekiston Fizika Zhurnali
Journal Volume
7
Journal Issue
1
Journal Page Range
p. 16-21
ISSN
1025-8817

Optional Information

Notes
12 refs., 1 tab., 2 figs.