Published April 2018
| Version v1
Journal article
Regioselective synthesis of pyridines by redox alkylation of pyridine N-oxides with malonates
- 1. University of Vienna, Institute of Organic Chemistry (Austria)
Description
A regioselective synthesis of pyridines by the addition of malonate anions to pyridine N-oxide derivatives, which have been activated by trifluoromethanesulfonic anhydride, is reported. The reaction selectively affords either 2- or 4-substituted pyridines in good yields. Graphical abstract: .
Additional details
Identifiers
Publishing Information
- Journal Title
- Monatshefte fuer Chemie
- Journal Volume
- 149
- Journal Issue
- 4
- Journal Page Range
- p. 715-719
- ISSN
- 0026-9247
- CODEN
- MOCHAP
Conference
- Title
- 17. blue Danube symposium on heterocyclic chemistry
- Dates
- 30 Aug - 2 Sep 2017
- Place
- Linz (Austria)
INIS
- Country of Publication
- Austria
- Country of Input or Organization
- Austria
- INIS RN
- 50003509
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S77: NANOSCIENCE AND NANOTECHNOLOGY;
- Resource subtype / Literary indicator
- Conference
- Descriptors DEI
- ALKYLATION; ANHYDRIDES; ANIONS; OXIDES; PYRIDINE; SYNTHESIS
- Descriptors DEC
- AZINES; CHALCOGENIDES; CHARGED PARTICLES; CHEMICAL REACTIONS; HETEROCYCLIC COMPOUNDS; IONS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; OXYGEN COMPOUNDS; PYRIDINES
Optional Information
- Copyright
- Copyright (c) 2018 The Author(s)