Natural versus anthropogenic influence on trace elemental concentration in precipitation at Dokriani Glacier, central Himalaya, India

Atmospheric pollutant transport and deposition at the Himalaya affects the climate, cryosphere, and monsoon patterns and impose an adverse impact over the Himalayan ecosystem. At present, the data on trace elements (TEs) concentrations and dynamics over the high-altitude Himalayan region are scarce and has received less attention. Therefore, in the present study, we investigated the TEs concentration and depositional pattern at Dokriani Glacier, central Himalaya to understand their levels, dynamics, and potential effects. A total of 39 samples were collected from two snowpit stratigraphies, deposited during non-monsoon period and monsoonal precipitation between 4530 to 4630 m a.s.l. altitude in the year 2017. The results of analyzed trace metals (Al, Cr, Mn, Fe, Sr, Co, Ni, Cu, Zn, Cd, As, and Pb) showed high enrichment values for Zn, Cr, Co, Ni and Mn compared to other parts of the Himalayan region, suggesting the influence of anthropogenic emissions (e.g., fossil fuel, metal production, and industrial processes) from urbanized areas of South Asia. Our results also revealed the possible health effects related to the enrichment of Zn and Cd, which may be responsible for skin-related diseases in Uttarakhand region. We attribute increasing anthropogenic activities in the environment to have a significant impact on the ecosystem health of the central Himalayan region. This study provides the baseline information on TEs concentration and sources in the Himalayas, which needs wide dissemination to scientific community as well as policymakers. Therefore, systematic observations, management, and preparing action plan to overcome the health effects from TEs pollution are urgently needed over the remote, pristine Himalayan region.