Published 2017 | Version v1
Journal article Metadata-only

A Mononuclear Nonheme Iron(V)-Imido Complex

Creators

  • 1. Sookmyung Women's University, Seoul (Korea, Republic of)
  • 2. Ewha Womans University, Seoul (Korea, Republic of)
  • 3. Stanford University, Stanford, CA (United States)

Description

Mononuclear nonheme iron(V)-oxo complexes have been reported previously. Herein, we report the first example of a mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [(TAML)FeV(NTs)]– . The spectroscopic characterization of 1 revealed an S = 1/2 Fe(V) oxidation state, an Fe—N bond length of 1.65(4) Å, and an Fe—N vibration at 817 cm–1. In conclusion, the reactivity of 1 was demonstrated in C—H bond functionalization and nitrene transfer reactions.

Availability note (English)

Available from http://www.osti.gov/pages/biblio/1374342; DOE Accepted Manuscript full text, or the publishers Best Available Version will be available free of charge after the embargo period

Additional details

Identifiers

URL
http://www.osti.gov/pages/biblio/1374342;
DOI
10.1021/jacs.7b04695;

Publishing Information

Journal Title
Journal of the American Chemical Society
Journal Volume
139
Journal Issue
26
Journal Page Range
p. 8800-8803
ISSN
0002-7863

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
49012697
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Resource subtype / Literary indicator
Numerical Data
Descriptors DEI
BOND LENGTHS; COMPLEXES; EXPERIMENTAL DATA; IRON; TRANSFER REACTIONS
Descriptors DEC
DATA; DIMENSIONS; DIRECT REACTIONS; ELEMENTS; INFORMATION; LENGTH; METALS; NUCLEAR REACTIONS; NUMERICAL DATA; TRANSITION ELEMENTS

Optional Information

Contract/Grant/Project number
AC02-76SF00515; 1-1603-2054; NRF-2010-00353; NRF-2012R1A3A2048842; NRF-2017R1C1B2002037; 15H00960; GM40392
Funding organization
USDOE (United States)
Secondary number(s)
OSTIID--1374342