Smart ion imprinted polymer for selective adsorption of Ru(Ⅲ) and simultaneously waste sample being transformed as a catalyst

Highlights: • Imprinted polymer containing PDEA-b-P(DEA-co-AM) can effectively realize the sol-gel phase transition. • The prepared imprinted polymer has good selectivity and reproducibility. • The discarded Ru-IIP was used as an effective catalyst to catalyze the formation of imines. In this work, a temperature-sensitive block polymer PDEA-b-P(DEA-co-AM) was synthesized and then introduced into the preparation of a smart Ru(Ⅲ) imprinted polymer (Ru-IIP) to selectively adsorption Ru(Ⅲ) first. Then the waste Ru-IIP was converted into a catalyst in-situ for recycle. The structure and morphology of the prepared polymer were characterized by Fourier transform infrared spectrometer, Scanning electron microscope, BET surface area and Thermogravimetric analysis. The adsorption properties of the synthesized smart material were investigated in terms of adsorption pH, adsorption kinetics and adsorption isotherm. Results documented that the optimal adsorption temperature and pH were 35 °C and 1.5 respectively, the maximum adsorption capacity was 0.153 mmol/g, and the adsorption processes of Ru-IIP were more suitable to be expressed by pseudo-first-order kinetic and Langmuir model. The selectivity studied in different binary mixed solutions showed that Ru-IIP has good selectivity, and reusability results showed that Ru-IIP still maintains a good adsorption effect after 8 cycles. In addition, the waste Ru-IIP, a Ru(Ⅲ) remained waste sample was employed as the catalyst for the synthesis of imines, and result showed the mass of adsorbent would reduce after the completion of catalysis, which could not only catalyze the reaction but also reduce pollution.