Kinetic-energy distribution of D(2p) atoms from analysis of the D Lyman-α line profile

The kinetic-energy distribution of D(2p) atoms resulting from electron-impact dissociation of D2 has been measured. A high-resolution vacuum ultraviolet spectrometer was employed for the first measurement of the D Lyman-α (D Lα) emission line profiles at 20- and 100-eV excitation energies. Analysis of the deconvoluted line profile of D Lα at 100 eV reveals the existence of a narrow line central peak of 29±2m Angstrom full width at half maximum and a broad pedestal wing structure about 190 m Angstrom wide. The wings of the line can be used to determine the fast atom distribution. The wings of D Lα arise from dissociative excitation of a series of doubly excited states that cross the Franck-Condon region between 23 and 40 eV. The fast atom distribution at 100-eV electron impact energy spans the energy range from 1 to 10 eV with a peak value near 6 eV. Slow D(2p) atoms characterized by a distribution function with peak energy near 100 meV produce the central peak profile, which is nearly independent of the impact energy. The deconvoluted line profiles of the central peak at 20 eV for dissociative excitation of D2 and H2 are fitted with an analytical function for use in calibration of space flight instrumentation equipped with a D/H absorption cell. The kinetic-energy and line profile results are compared to similar measurements for H2. The absolute cross sections for the line center (slow atoms) and wings (fast atoms) and total emission line profile were measured from threshold to 400 eV. Analytical model coefficients are given for the energy dependence of the measured slow atom cross section. copyright 1997 The American Physical Society