Published August 2007 | Version v1
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Syntheses of environmentally friendly amide derivatives for the selective separation of actinides based on oxidation states

Description

Syntheses of environmentally friendly amide derivatives for the selective separation of actinides were studied. As for the ligand, we have synthesized TODGA (N,N-Tetraoctyl diglycolamide), DHOA (N,N-Dihexyloctaneamide), and D2EHBA (N,N-Di(2-ethyl)hexylbutanamide) in high yield. The amide derivative was successfully prepared by chlorination followed by amination method in a good synthetic yield. The structures of all synthetic precursors and final products were confirmed by NMR, IR, and Mass spectrophotometer

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Available from INIS in electronic form; Also available from KAERI

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Additional details

Publishing Information

Imprint Pagination
52 p.
Report number
KAERI/CM--1003/2006

INIS

Country of Publication
Korea, Republic of
Country of Input or Organization
Korea, Republic of
INIS RN
39082461
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
ACTINIDES; AMIDES; CHLORINATION; DERIVATIZATION; EXTRACTION; OXIDATION
Descriptors DEC
CHEMICAL REACTIONS; ELEMENTS; HALOGENATION; METALS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; SEPARATION PROCESSES

Optional Information

Notes
29 refs, 15 figs