Published August 1987 | Version v1
Journal article Metadata-only

Preparation of nitrogenous, hydride and carbonyl molybdenum and tungsten complexes from higher halides

Creators

  • 1. AN SSSR, Chernogolovka. Inst. Novykh Khimicheskikh Problem

Description

Reduction of molybdenum pentachloride and tungsten hexachloride with metallic Mg in THF in the presence of tertiary organic phosphines in N2, H2 or CO atmosphere has been studied. It is shown that this method is convenient for preparing nitrogeneous M(N2)2L4, hydride MN4L4 and carbonyl M(CO)6-xLx (M=Mo, W; L - tertiary organic phosphine) complexes of molybdenum and tungsten. Physico-chemical characteristics of complexes prepared are presented

Additional details

Additional titles

Original title (Russian)
Получение азотных, гидридных и карбонильных комплексов молибдена и вольфрама из высших галогенидов

Publishing Information

Journal Title
Zh. Obshch. Khim.
Journal Volume
57
Journal Issue
8
Series
Zh. Obshch. Khim.
Journal Page Range
1688-1693
ISSN
0044-460X
CODEN
ZOKHA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
19039699
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CARBONYLS; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CHEMICAL REACTION YIELD; HYDRIDES; INFRARED SPECTRA; LIGANDS; MELTING POINTS; MOLYBDENUM COMPLEXES; NITROGEN; ORGANIC PHOSPHORUS COMPOUNDS; TETRAHYDROFURAN; TUNGSTEN COMPLEXES
Descriptors DEC
COMPLEXES; ELEMENTS; FURANS; HETEROCYCLIC COMPOUNDS; HYDROGEN COMPOUNDS; NONMETALS; ORGANIC COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; SPECTRA; SYNTHESIS; THERMODYNAMIC PROPERTIES; TRANSITION ELEMENT COMPLEXES; TRANSITION TEMPERATURE