Published September 1986
| Version v1
Journal article
Kinetic model and mathematical description of oligomerization of ethylene to higher linear alpha-olefins, catalyzed by the system Zr(OCOiso-C3H7)-(C2H5)3AL2CL3
Description
The authors have formulated a mathematical model of ethylene oligomerization in the presence of the system Zr (OCOR)4 - (C2H5)3AL2CL3, worked out an approximate analytical description of the kinetic relationships of ethylene consumption in the course of its oligomerization in presence of this system, and estimated the effective rate constants of the principal oligomerization stages
Additional details
Publishing Information
- Journal Title
- J. Appl. Chem. USSR (Engl. Transl.)
- Journal Volume
- 59
- Journal Issue
- 2,PT.2
- Series
- J. Appl. Chem. USSR (Engl. Transl.).
- Journal Page Range
- 332-336
- ISSN
- 0021-888X
- CODEN
- JAPUA
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 18034972
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ALKENES; ALUMINIUM CHLORIDES; CATALYSIS; CHEMICAL REACTION KINETICS; CHEMICAL REACTION YIELD; ETHYLENE; MATHEMATICAL MODELS; ORGANOMETALLIC COMPOUNDS; POLYMERIZATION; ZIRCONIUM COMPLEXES
- Descriptors DEC
- ALUMINIUM COMPOUNDS; CHEMICAL REACTIONS; CHLORIDES; CHLORINE COMPOUNDS; COMPLEXES; HALIDES; HALOGEN COMPOUNDS; HYDROCARBONS; KINETICS; ORGANIC COMPOUNDS; REACTION KINETICS; TRANSITION ELEMENT COMPLEXES
Optional Information
- Notes
- Cover-to-cover translation of Zhurnal Prikladnoj Khimii (USSR).