Published December 15, 1975 | Version v1
Journal article

Comment on ''Semiclassical treatment of vibrational--translational energy transfer in the near-adiabatic approximation''

  • 1. Department of Chemistry, Indiana-Purdue University at Indianapolis, Indianapolis, Indiana 46205

Description

Recently a near-adiabatic (perturbed stationary states) approximation was used in an investigation the collinear vibrational excitation of a harmonic oscillator. This approximation reduced the problem to that of obtaining transition probabilities for a harmonic oscillator with time-dependent forcing function. Cady derived an apparently exact solution for this problem. It is shown that this solution is not exact but that the solution results from making a further adiabatic approximation and a derivation is given that clearly shows the adiabatic character of this further approximation

Additional details

Identifiers

Publishing Information

Journal Title
The Journal of Chemical Physics
Journal Volume
63
Journal Issue
12
Series
J. Chem. Phys.
Journal Page Range
5505-5506
ISSN
0021-9606

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
7245327
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Descriptors DEI
ENERGY TRANSFER; HARMONIC OSCILLATORS; MOLECULE COLLISIONS; SEMICLASSICAL APPROXIMATION; VIBRATIONAL STATES
Descriptors DEC
COLLISIONS; ENERGY LEVELS; EXCITED STATES

Optional Information

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