Published December 15, 1975
| Version v1
Journal article
Comment on ''Semiclassical treatment of vibrational--translational energy transfer in the near-adiabatic approximation''
Creators
- 1. Department of Chemistry, Indiana-Purdue University at Indianapolis, Indianapolis, Indiana 46205
Description
Recently a near-adiabatic (perturbed stationary states) approximation was used in an investigation the collinear vibrational excitation of a harmonic oscillator. This approximation reduced the problem to that of obtaining transition probabilities for a harmonic oscillator with time-dependent forcing function. Cady derived an apparently exact solution for this problem. It is shown that this solution is not exact but that the solution results from making a further adiabatic approximation and a derivation is given that clearly shows the adiabatic character of this further approximation
Additional details
Identifiers
- DOI
- 10.1063/1.431293;
Publishing Information
- Journal Title
- The Journal of Chemical Physics
- Journal Volume
- 63
- Journal Issue
- 12
- Series
- J. Chem. Phys.
- Journal Page Range
- 5505-5506
- ISSN
- 0021-9606
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 7245327
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- ENERGY TRANSFER; HARMONIC OSCILLATORS; MOLECULE COLLISIONS; SEMICLASSICAL APPROXIMATION; VIBRATIONAL STATES
- Descriptors DEC
- COLLISIONS; ENERGY LEVELS; EXCITED STATES
Optional Information
- Notes
- Updated automatically by Metadata and Full-Text Enrichment Agent