Published September 1984 | Version v1
Journal article Metadata-only

Interaction of tantalum and niobium pentachlorides with ethyl alcohol

Creators

  • 1. Gosudarstvennyj Nauchno-Issledovatel'skij i Proektnyj Inst. Redkometallicheskoj Promyshlennosti, Moscow (USSR)

Description

It has been established, that in the process of interaction between tantalum and niobium and ethanol the following compounds (oxohydroxochlorenthylates) of brutto-formula Me2O3 (C2H5O)2(OH)Cl are formed. Two alternative formulas with the accuracy up to the position of substituents in metal atoms can correspond to the composition. The structure assumed has been refined using the methods of IR- and UV-spectroscopy. A high solubility of tantalum and niobium oxohydroxochlorethylates in ethanol is pointed out. Temperature dependence of density and viscosity of alcohol solutions of pentachlorides and oxohydroxochlorethylates is studied

Additional details

Additional titles

Original title (Russian)
Взаимодействие пентахлоридов тантала и ниобия с этиловым спиртом

Publishing Information

Journal Title
Zh. Neorg. Khim.
Journal Volume
29
Journal Issue
9
Series
Zh. Neorg. Khim.
Journal Page Range
2256-2260
ISSN
0044-457X

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
16057010
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CHEMICAL COMPOSITION; CHEMICAL REACTION KINETICS; CHEMICAL REACTIONS; DENSITY; ETHANOL; INFRARED SPECTRA; MEDIUM TEMPERATURE; NIOBIUM CHLORIDES; SOLUBILITY; SOLUTIONS; TANTALUM CHLORIDES; TEMPERATURE DEPENDENCE; VISCOSITY
Descriptors DEC
ALCOHOLS; CHLORIDES; CHLORINE COMPOUNDS; DISPERSIONS; HALIDES; HALOGEN COMPOUNDS; HOMOGENEOUS MIXTURES; HYDROXY COMPOUNDS; KINETICS; MIXTURES; NIOBIUM COMPOUNDS; ORGANIC COMPOUNDS; PHYSICAL PROPERTIES; REACTION KINETICS; SPECTRA; TANTALUM COMPOUNDS; TRANSITION ELEMENT COMPOUNDS

Optional Information

Notes
For English translation see the journal Russian Journal of Inorganic Chemistry (UK).