Published January 2019
| Version v1
Journal article
Trifluoroacetylation of N-Substituted 1H-1,2-Diazaphenalenes of the Naphthalene and Acenaphthene Series
Creators
- 1. Southern Federal University, Research Institute of Physical and Organic Chemistry (Russian Federation)
- 2. Russian Academy of Sciences, Kurnakov Institute of General and Inorganic Chemistry (Russian Federation)
Description
The acylation of N-substituted 3-methyl-1H-1,2-diazaphenalenes of the naphthalene and acenaphthene series with trifluoroacetic anhydride gave mono- and diacylated products. Despite the presence of a bulky substituent on the pyrrole type nitrogen atom, the trifluoroacetyl group entered the peri position with respect to that substituent. The product structure was confirmed by X-ray analysis.
Additional details
Identifiers
Publishing Information
- Journal Title
- Russian Journal of Organic Chemistry
- Journal Volume
- 55
- Journal Issue
- 1
- Journal Page Range
- p. 87-92
- ISSN
- 1070-4280
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 51108818
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ACENAPHTHENE; ACYLATION; ANHYDRIDES; ATOMS; NAPHTHALENE; NITROGEN; PYRROLES; X RADIATION
- Descriptors DEC
- AROMATICS; AZOLES; CHEMICAL REACTIONS; ELECTROMAGNETIC RADIATION; ELEMENTS; HETEROCYCLIC COMPOUNDS; HYDROCARBONS; IONIZING RADIATIONS; NONMETALS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; POLYCYCLIC AROMATIC HYDROCARBONS; RADIATIONS
Optional Information
- Copyright
- Copyright (c) 2019 Pleiades Publishing, Ltd.