Published April 2021 | Version v1
Journal article

Removal of uranium(VI) from simulated wastewater by a novel porous membrane based on crosslinked chitosan, UiO-66-NH2 and polyvinyl alcohol

  • 1. Southwest University of Science and Technology, Mianyang (China). State Key Laboratory of Environment-Friendly Energy Materials, Engineering Research Center of Biomass Materials, Ministry of Education, and School of Materials Science and Engineering
  • 2. Sichuan University, Chengdu (China). School of Chemical Engineering

Description

The development of highly efficient adsorbent presents an enticing prospect for U(VI)-containing radioactive wastewater treatment. In this work, a novel porous cCS/PVA/UiO-66-NH2 membrane absorbent comprising of crosslinked chitosan (cCS), polyvinyl alcohol (PVA) and UiO-66-NH2 is designed and prepared. The adsorption capacity of porous cCS/PVA/UiO-66-H2 membrane achieves 316.50 mg g-1 under an optimal condition. Furthermore, the porous cCS/PVA/UiO-66-NH2 membrane exhibits a high selectivity for U(VI) adsorption in simulated radioactive wastewater treatment. The possible mechanism of U(VI) adsorption onto porous cCS/PVA/UiO-66-NH2 membrane mainly includes surface complexation and cation exchange processes. In addition, the porous cCS/PVA/UiO-66-NH2 membrane also exhibits excellent cycling adsorption-desorption performance. All these results demonstrate that the porous cCS/PVA/UiO-66-NH2 membrane is a promising candidate for application in U(VI) removal from radioactive wastewater. (author)

Additional details

Publishing Information

Journal Title
Journal of Radioanalytical and Nuclear Chemistry
Journal Volume
328
Journal Issue
1
Journal Page Range
p. 397-410
ISSN
0236-5731
CODEN
JRNCDM

Optional Information

Notes
52 refs.