Removal of uranium(VI) from simulated wastewater by a novel porous membrane based on crosslinked chitosan, UiO-66-NH2 and polyvinyl alcohol
Creators
- 1. Southwest University of Science and Technology, Mianyang (China). State Key Laboratory of Environment-Friendly Energy Materials, Engineering Research Center of Biomass Materials, Ministry of Education, and School of Materials Science and Engineering
- 2. Sichuan University, Chengdu (China). School of Chemical Engineering
Description
The development of highly efficient adsorbent presents an enticing prospect for U(VI)-containing radioactive wastewater treatment. In this work, a novel porous cCS/PVA/UiO-66-NH2 membrane absorbent comprising of crosslinked chitosan (cCS), polyvinyl alcohol (PVA) and UiO-66-NH2 is designed and prepared. The adsorption capacity of porous cCS/PVA/UiO-66-H2 membrane achieves 316.50 mg g-1 under an optimal condition. Furthermore, the porous cCS/PVA/UiO-66-NH2 membrane exhibits a high selectivity for U(VI) adsorption in simulated radioactive wastewater treatment. The possible mechanism of U(VI) adsorption onto porous cCS/PVA/UiO-66-NH2 membrane mainly includes surface complexation and cation exchange processes. In addition, the porous cCS/PVA/UiO-66-NH2 membrane also exhibits excellent cycling adsorption-desorption performance. All these results demonstrate that the porous cCS/PVA/UiO-66-NH2 membrane is a promising candidate for application in U(VI) removal from radioactive wastewater. (author)
Additional details
Publishing Information
- Journal Title
- Journal of Radioanalytical and Nuclear Chemistry
- Journal Volume
- 328
- Journal Issue
- 1
- Journal Page Range
- p. 397-410
- ISSN
- 0236-5731
- CODEN
- JRNCDM
INIS
- Country of Publication
- Hungary
- Country of Input or Organization
- Hungary
- INIS RN
- 52044531
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ADSORPTION; ION EXCHANGE; MEMBRANES; POLYSACCHARIDES; PVA; RADIOACTIVE WASTES; URANIUM; WASTE WATER
- Descriptors DEC
- ACTINIDES; ALCOHOLS; CARBOHYDRATES; ELEMENTS; HYDROGEN COMPOUNDS; HYDROXY COMPOUNDS; LIQUID WASTES; MATERIALS; METALS; ORGANIC COMPOUNDS; ORGANIC POLYMERS; OXYGEN COMPOUNDS; POLYMERS; POLYVINYLS; RADIOACTIVE MATERIALS; SACCHARIDES; SORPTION; WASTES; WATER
Optional Information
- Notes
- 52 refs.