Published July 1987 | Version v1
Journal article Metadata-only

Preparation and properties of lithium intercalated compounds on the base of niobium trichalcogenides

Creators

  • 1. AN SSSR, Novosibirsk. Inst. Neorganicheskoj Khimii

Description

Interaction of low-dimensional niobium trisulfide and triselenide with n-butyl-lithium in hexane has been studied. Lithium intercalated compounds prepared are characterized by different methods of physico-chemical analysis. Intercalated compounds thermal stability is determined. Diffusion mobility of lithium ion in matrix has been studied by the method of NMR relaxation; the activation energy calculated (∼ 3.2 kcal/mol) is one the lowest energies among the known lithium compounds

Additional details

Additional titles

Original title (Russian)
Получение и свойства литиевых интеркалатов на основе трихалькогенидов ниобия

Publishing Information

Journal Title
Zh. Neorg. Khim.
Journal Volume
32
Journal Issue
7
Series
Zh. Neorg. Khim.
Journal Page Range
1591-1595
ISSN
0044-457X
CODEN
ZNOKA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
19031121
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ACTIVATION ENERGY; CHALCOGENIDES; CHEMICAL PREPARATION; CLATHRATES; CRYSTAL STRUCTURE; DIFFUSION; LAYERS; LITHIUM COMPOUNDS; MATRIX MATERIALS; NIOBIUM COMPOUNDS; SENSITIVITY; THERMAL DEGRADATION
Descriptors DEC
ALKALI METAL COMPOUNDS; ENERGY; MATERIALS; SYNTHESIS; TRANSITION ELEMENT COMPOUNDS