Published August 16, 1991 | Version v1
Journal article Metadata-only

Radiation-induced gas-phase dealkylation and isomerization of p-tert-butyltoluene

Creators

  • 1. Consiglio Nazionale delle Ricerche, Rome (Italy). Ist. di Cromatografia
  • 2. Consiglio Nazionale delle Ricerche, Rome (Italy). Ist. di Chimica Nucleare

Description

D3+ ions, produced by deuterium γ-radiolysis, were allowed to react with gaseous p-tert-butyltoluene. The excited arenium ions formed, if not collisionally stabilized, underwent predominantly dealkylation to form toluene and, to a minor extent, isomerization. The dependence of reaction product yields on the substrate pressure is discussed. (author) 12 refs

Additional details

Publishing Information

Journal Title
Journal of Radioanalytical and Nuclear Chemistry
Journal Volume
154
Journal Issue
6
Series
J. Radioanal. Nucl. Chem. ;Letters.
Journal Page Range
421-426
ISSN
0236-5731
CODEN
JRNCD

INIS

Country of Publication
Hungary
Country of Input or Organization
Hungary
INIS RN
23029920
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Resource subtype / Literary indicator
Numerical Data
Descriptors DEI
ALKYL RADICALS; CHEMICAL REACTION YIELD; DEALKYLATION; DEUTERIUM IONS; EXPERIMENTAL DATA; G VALUE; GAMMA RADIATION; ISOMERIZATION; RADIATION DOSES; RADIOLYSIS; SUBSTRATES; TOLUENE; TRACER TECHNIQUES; TRITIUM
Descriptors DEC
AROMATICS; BETA DECAY RADIOISOTOPES; BETA-MINUS DECAY RADIOISOTOPES; CHARGED PARTICLES; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; DATA; DECOMPOSITION; ELECTROMAGNETIC RADIATION; HYDROCARBONS; HYDROGEN ISOTOPES; INFORMATION; IONIZING RADIATIONS; IONS; ISOTOPE APPLICATIONS; ISOTOPES; LIGHT NUCLEI; NUCLEI; NUMERICAL DATA; ODD-EVEN NUCLEI; ORGANIC COMPOUNDS; RADIATION EFFECTS; RADIATIONS; RADICALS; RADIOISOTOPES; YEARS LIVING RADIOISOTOPES