Published March 2005
| Version v1
Journal article
A novel hybrid crystal of chiral racemic complexes coexisting with two kinds of polyoxomolybdates: synthesis and structure of [Co(bpy)3]2[Mo6O19] [β-(H2Mo8O26)].4H2O
- 1. Department of Chemistry, Baicheng Teacher's College, Baicheng, 137000 (China)
- 2. Department of Chemistry, Northeast Normal University, Number 138, Renmin Street, Changchun City, Jilin province 130024 (China)
- 3. State Key Laboratory for Structural Chemistry of Unstable and Stable Species Institute of Physical Chemistry, College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871 (China)
Description
A novel polyoxometalate-based organic-inorganic hybrid compound, [Co(bpy)3]2 [Mo6O19] [β-(H2Mo8O26)].4H2O (1), have been hydrothermally synthesized and structurally characterized by elemental analysis, single-crystal X-ray diffraction, IR and X-ray photoelectron spectra. Compound 1 represents the first example that racemic complexes coexisting with two kinds of polyoxomolybdate anions in the same crystal architecture, which should be of rare chance that four kinds of complexes crystallizes into a compound
Additional details
Identifiers
- DOI
- 10.1016/j.jssc.2004.11.034;
- PII
- S0022-4596(04)00631-0;
Publishing Information
- Journal Title
- Journal of Solid State Chemistry
- Journal Volume
- 178
- Journal Issue
- 3
- Journal Page Range
- p. 608-612
- ISSN
- 0022-4596
- CODEN
- JSSCBI
INIS
- Country of Publication
- United States
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 37037258
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CHIRALITY; COBALT COMPLEXES; CRYSTAL STRUCTURE; HYDROTHERMAL SYNTHESIS; MOLYBDATES; MONOCRYSTALS; RACEMATES; X-RAY DIFFRACTION; X-RAY PHOTOELECTRON SPECTROSCOPY
- Descriptors DEC
- COHERENT SCATTERING; COMPLEXES; CRYSTALS; DIFFRACTION; ELECTRON SPECTROSCOPY; MOLYBDENUM COMPOUNDS; OXYGEN COMPOUNDS; PARTICLE PROPERTIES; PHOTOELECTRON SPECTROSCOPY; REFRACTORY METAL COMPOUNDS; SCATTERING; SPECTROSCOPY; SYNTHESIS; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENT COMPOUNDS
Optional Information
- Copyright
- Copyright (c) 2005 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.