Published October 1981 | Version v1
Report

Recent advances in isotope separation. Uranium enrichment and tritium separation by chemical exchange and plasma separation

  • 1. Institute of Physical and Chemical Research, Wako, Saitama (Japan)

Description

Isotope separation effect for uranium by chemical exchange had been found to be too small for practical applications. However, Japan developed recently a promising uranium enrichment process based on chemical exchange, which is an ion exchange reaction between uranous ion in an anion resin bed and uranyl ion in solution. Development of a water-hydrogen exchange process has been eagerly anticipated as technology for large scale separation of tritium. This paper reviews recent studies which have resulted in the development of highly active hydrophobic platinum catalysts. The research concerning isotope separation in plasma has been in progress. In this area two schemes - plasma rotation and ion cyclotron resonance - show the most promising results. However, one cannot presently be sure that these methods will lead to an economical large scale separation, because the physics is more complex than that involved in other separation techniques

Availability note (English)

Available from CEN Saclay, Service de Documentation, 91191 Gif-sur-Yvette Cedex (France).

Abstract (French)

On a trouve que l'effet de separation isotopique de l'uranium par le procede d'echange chimique est trop faible pour son application pratique. Toutefois on a developpe recemment au Japon un procede d'enrichissement de l'uranium prometteur base sur l'echange chimique qui est une reaction d'echange entre des ions uraneux dans un lit de resine anionique et des ions uranyle en solution. On attend beaucoup du developpement du procede d'echange eau-hydrogene comme technologie pour la separation du tritium sur une grande echelle. On passe en revue les etudes recentes concernant le developpement de catalyseurs au platine hydrophobes et tres actifs. Les recherches concernant la separation isotopique dans les plasmas progressent. Dans ce domaine deux procedes (rotation de plasma et resonance gyromagnetique ionique) retiennent l'attention. Toutefois, on ne peut encore etre assure que ces procedes seront economiques industriellement parce qu'ils sont plus complexes que ceux employes actuellement

Additional details

Additional titles

Original title (French)
Les progres recents accomplis dans la separation des isotopes. L'enrichissement de l'uranium et la separation du tritium par le procede d'echange chimique et la methode de separation par plasma

Publishing Information

Imprint Pagination
11 p.
Report number
CEA-TR--3-256-0

INIS

Country of Publication
France
Country of Input or Organization
France
INIS RN
13674300
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Resource subtype / Literary indicator
Non-conventional Literature
Descriptors DEI
CHEMICAL REACTIONS; ISOTOPE SEPARATION; PLASMA; TRITIUM; URANIUM
Descriptors DEC
ACTINIDES; BETA DECAY RADIOISOTOPES; BETA-MINUS DECAY RADIOISOTOPES; ELEMENTS; HYDROGEN ISOTOPES; ISOTOPES; LIGHT NUCLEI; METALS; NUCLEI; ODD-EVEN NUCLEI; RADIOISOTOPES; SEPARATION PROCESSES; YEARS LIVING RADIOISOTOPES

Optional Information

Notes
Translated from Oyo Butsuri, 1980, v. 49(8), p. 754-767.