Published January 1991 | Version v1
Journal article

Electronic structure of clusters with 3d-elements in layered oxide systems

  • 1. AN SSSR, Sverdlovsk (Russian Federation). Inst. Khimii
  • 2. Sverdlovskij Pedagogicheskij Inst., Sverdlovsk (Russian Federation)

Description

Cluster method of descrete variation was used to calculate characteristic structural polyhedrons in LaSrCuO4, simulating the electron structure of both copper centers and other 3d-elements (Ti-Ni) in 2 and 3 oxidation degrees in the lattice of the given superconductor. Regularities of formation of valent O2p- and M3d-states are considered. Possibility of production of systems with p-type and n-type conduction, based on element oxides with partially occupied 3d-shell is evaluated

Additional details

Additional titles

Original title (Russian)
Электронное строение кластеров 3d-элементов в слоистых оксидных системах

Publishing Information

Journal Title
Zhurnal Strukturnoj Khimii
Journal Volume
32
Journal Issue
1
Series
Zh. Strukt. Khim.
Journal Page Range
20-25
ISSN
0136-7463
CODEN
ZSTKA