Published August 1990 | Version v1
Journal article Metadata-only

Physicochemical study of properties of complex oxides of the system Li2O-MoO3-SnO2

Creators

  • 1. Moskovskij Inst. Tonkoj Khimicheskoj Tekhnologii, Moscow (USSR)

Description

By the method of differential thermal analysis using X-ray phase analysis in the Li2O-MoO3-SnO2 system (Li2Sn(MoO4)3-Sn(MoO4)2 cross section) formation of a new complex of the composition Li2Sn3(MoO4)7 incongruently melting at 480 deg C is ascertained. IR, Raman and NMR spectra of Li4SnMo2O10, Li2Sn(MoO4)3 and Li2Sn3(MoO4)7 complex oxides are presented. According to 7Li NMR spectra of Li4SnMo2O10, Li2Sn(MoO4)3 and Li2Sn3(MoO4)7 complex are presented. According to 7Li NMR spectra the value of the lithium diffusion increases in the series Li4SnMo2O10→Li2Sn(MoO4)3→Li2Sn3(MoO4)7

Additional details

Additional titles

Original title (Russian)
Физико-химическое изучение свойств сложных оксидов системы Ли

Publishing Information

Journal Title
Zhurnal Neorganicheskoj Khimii
Journal Volume
35
Journal Issue
8
Series
Zh. Neorg. Khim.
Journal Page Range
2151-2155
ISSN
0044-457X
CODEN
ZNOKA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
22041774
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CHEMICAL COMPOSITION; CHEMICAL REACTIONS; DIFFUSION; INFRARED SPECTRA; LITHIUM OXIDES; MELTING POINTS; MOLYBDENUM OXIDES; NMR SPECTRA; PHASE DIAGRAMS; RAMAN SPECTRA; TIN OXIDES; VIBRATIONAL STATES
Descriptors DEC
ALKALI METAL COMPOUNDS; CHALCOGENIDES; DIAGRAMS; ENERGY LEVELS; EXCITED STATES; INFORMATION; LITHIUM COMPOUNDS; MOLYBDENUM COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; SPECTRA; THERMODYNAMIC PROPERTIES; TIN COMPOUNDS; TRANSITION ELEMENT COMPOUNDS; TRANSITION TEMPERATURE