Published June 16, 1997 | Version v1
Journal article Metadata-only

Silver-tellurolate polynuclear complexes: from isolated cluster units to extended polymer chains

Creators

  • 1. Karlsruhe Univ. (T.H.) (Germany). Inst. fuer Anorganische Chemie
  • 2. Waterloo Univ., ON (Canada). Dept. of Chemistry

Description

In the presence of tertiary phosphanes, AgCl reacts readily with the reagent Te(Ph)SiMe3 to yield silver - tellurolate polynuclear complexes. In the case of PMe3, the polymer [Ag10(μ3-TePh)10(PMe3)2]∞ (shown below) is formed, in which the TePh ligands seve as both inter- and intracluster bridges. (orig.)

Additional details

Publishing Information

Journal Title
Chemistry (Weinheim)
Journal Volume
36
Journal Issue
11
Journal Page Range
p. 1176-1179.
ISSN
0947-6539
CODEN
CEUJED

INIS

Country of Publication
Germany
Country of Input or Organization
Germany
INIS RN
28058623
Subject category
S36: MATERIALS SCIENCE;
Descriptors DEI
CHEMICAL PREPARATION; INTERMOLECULAR FORCES; MOLECULAR STRUCTURE; PHOSPHORUS 31; POLYMERS; SILVER COMPOUNDS; SOLID CLUSTERS; TELLURIUM COMPLEXES; TELLURIUM COMPOUNDS; YIELDS
Descriptors DEC
COMPLEXES; ISOTOPES; LIGHT NUCLEI; NUCLEI; ODD-EVEN NUCLEI; PHOSPHORUS ISOTOPES; STABLE ISOTOPES; SYNTHESIS; TRANSITION ELEMENT COMPOUNDS