Published June 14, 2016 | Version v1
Journal article

An alternative realization of the exact non-Markovian stochastic Schrödinger equation

  • 1. Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, Chinese Academy of Sciences, Zhongguancun, Beijing 100190, China and University of Chinese Academy of Sciences, Beijing 100049 (China)

Description

Based on the path integral approach, we derive a new realization of the exact non-Markovian stochastic Schrödinger equation (SSE). The main difference from the previous non-Markovian quantum state diffusion (NMQSD) method is that the complex Gaussian stochastic process used for the forward propagation of the wave function is correlated, which may be used to reduce the amplitude of the non-Markovian memory term at high temperatures. The new SSE is then written into the recently developed hierarchy of pure states scheme, in a form that is more closely related to the hierarchical equation of motion approach. Numerical simulations are then performed to demonstrate the efficiency of the new method.

Additional details

Identifiers

Publishing Information

Journal Title
Journal of Chemical Physics
Journal Volume
144
Journal Issue
22
Journal Page Range
vp.
ISSN
0021-9606
CODEN
JCPSA6

INIS

Country of Publication
United States
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
49006204
Subject category
S71: CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS;
Descriptors DEI
COMPUTERIZED SIMULATION; EQUATIONS OF MOTION; PATH INTEGRALS; PURE STATES; SCHROEDINGER EQUATION; WAVE FUNCTIONS
Descriptors DEC
DIFFERENTIAL EQUATIONS; EQUATIONS; FUNCTIONS; INTEGRALS; PARTIAL DIFFERENTIAL EQUATIONS; QUANTUM STATES; SIMULATION; WAVE EQUATIONS

Optional Information

Notes
(c) 2016 Author(s)