Published August 20, 1987
| Version v1
Journal article
1-phenyl-4,4-dimethyl-1,4-phosphasilacyclohexane and its selenide
- 1. Irkutsk Institute of Organic Chemistry, USSR
Description
1-phenyl-4,4-dimethyl-1,4-phosphasilacyclohexane was formed upon the photochemical addition of phenylphosphine to dimethyl(divinyl)silane and gave 1-phenyl-4,4-dimethyl-1-seleno-1,4-phosphasilacyclohexane upon reaction with elemental selenium. NMR spectroscopy indicated that 1-phenyl-4,4-dimethyl-1,4-phosphasilacyclohexane and 1-phenyl-4,4-dimethyl-1-seleno-1,4-phosphasilacyclohexane exist in the chair conformation with predominance of the conformer with axial orientation of the unshared electron pair of the phosphorus atom
Additional details
Publishing Information
- Journal Title
- Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.)
- Journal Volume
- 36
- Journal Issue
- 2
- Series
- Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.).
- Journal Page Range
- 409-411
- ISSN
- 0568-5230
- CODEN
- BACCA
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 19026501
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- CARBON 13; CHEMICAL SHIFT; COUPLING CONSTANTS; CYCLOALKANES; CYCLOHEXANE; DEUTERIUM COMPOUNDS; ELECTRONIC STRUCTURE; HYDROGEN 1; HYPERFINE STRUCTURE; ISOTOPE EFFECTS; J-J COUPLING; MASS SPECTRA; MOLECULAR STRUCTURE; NMR SPECTRA; ORGANIC PHOSPHORUS COMPOUNDS; PHOSPHORUS 31; PHOTOCHEMISTRY; SELENIUM COMPLEXES; SILICON COMPLEXES; SILICON 29; SYNTHESIS
- Descriptors DEC
- ALKANES; CARBON ISOTOPES; CHEMISTRY; COMPLEXES; COUPLING; EVEN-ODD NUCLEI; HYDROCARBONS; HYDROGEN COMPOUNDS; HYDROGEN ISOTOPES; INTERMEDIATE COUPLING; ISOTOPES; LIGHT NUCLEI; NUCLEI; ODD-EVEN NUCLEI; ORGANIC COMPOUNDS; PHOSPHORUS ISOTOPES; SILICON ISOTOPES; SPECTRA; STABLE ISOTOPES
Optional Information
- Notes
- Translated from Izestiya Akademii Nauk SSSR, Seriya Khimicheskaya; 36: No. 2, 451-453(Feb 1987).