Published February 1990 | Version v1
Book Metadata-only

Spectrophotometric determination of palladium in plutonium solutions by di-octyl sulfide extraction (Paper No. RA-16)

Creators

  • 1. Bhabha Atomic Research Centre, Bombay (India). Radiochemistry Div.

Description

A spectrophotometric method using di-octylsulphide was developed for the determination of palladium in nitric acid medium. The optimum acid range for the determination was found to be 0.4 to 3.5 M. The metal to ligand ratio was found to be 1:2. The molar absorptivity was found to be 1x104 1/mol/cm. Beer's law was found to be obeyed in the range of 1 to 100 μg of palladium. The RSD obtained at 16μg of palladium was 6%. (author)

Additional details

Publishing Information

Publisher
Bhabha Atomic Research Centre.
Imprint Place
Bombay (India)
Imprint Pagination
2 p.

Conference

Title
Symposium on radiochemistry and radiation chemistry.
Dates
5-8 Feb 1990.
Place
Nagpur (India).

INIS

Country of Publication
India
Country of Input or Organization
India
INIS RN
22041533
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Resource subtype / Literary indicator
Conference
Descriptors DEI
ABSORPTION SPECTRA; ACCURACY; AQUEOUS SOLUTIONS; LIGANDS; NITRIC ACID; ORGANIC SULFUR COMPOUNDS; PALLADIUM; PLUTONIUM; QUANTITATIVE CHEMICAL ANALYSIS; SOLVENT EXTRACTION; SPECTROPHOTOMETRY; URANIUM
Descriptors DEC
ACTINIDES; CHEMICAL ANALYSIS; DISPERSIONS; ELEMENTS; HOMOGENEOUS MIXTURES; HYDROGEN COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; METALS; MIXTURES; NITROGEN COMPOUNDS; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; PLATINUM METALS; SEPARATION PROCESSES; SOLUTIONS; SPECTRA; TRANSITION ELEMENTS; TRANSURANIUM ELEMENTS