Quality control assurance of strontium-90 in foodstuffs by LSC

A method based on the separation of Sr-90 by extraction chromatography and beta determination by Liquid Scintillation Counting (LSC) technique was used for strontium analysis in food samples. The methodology consisted in prior sample treatment (drying and incineration) followed by radiochemical separation of Sr-90 by extraction chromatography, using the Sr-resin. The chemical yield was determined by gravimetric method, adding stable strontium to the matrix. Beta activity (Sr-90/Y-90) was determined using a low background liquid scintillation spectrometer (Tri-Carb 3170 TR/SL, Packard). The accuracy and the precision of the method, was performed previously through recovery trials with Sr-90 spiked samples, using the same type of matrices (milk, complete meals, meat and vegetables). A reference material (IAEA₃21) was now used to measure the accuracy of the procedure. Participation in interlaboratory comparison exercises was also performed in order to establish an external control on the measurements and to ensure the adequacy of the method. - Highlights: • Blank and background samples were analyzed according to internal quality control program established. • Analysis of certified reference material was carried out to perform additional evaluation of the accuracy. • Analysis of interlaboratory comparison sample showed Z-score and Z (ML) acceptable values. • The Sr-90 activity measured in wild bilberry powder sample was in agreement with the reference value