Published October 1980
| Version v1
Journal article
Cs2DyCl5, an ino-chlorodysprosate(III) with extended cis-Zweier-Einfach-chains of octahedra
Description
Cs2DyCl5, colourless, hygroscopic, crystallizes orthorhombic (Pbnm, No. 62, Z = 4) with a = 1523.1, b = 954.9, c = 749.8 pm, Vsub(m) = 164.2 cm3 mol-1. Extended cis-bridged Zweier-Einfach-chains of octahedra sub(infinite)sup(1)[DyCl(1)sub(2/2)Cl(2)sub(2/1)Cl(3)sub(1/1)Cl(4)sub(1/1)] are connected by Cs+. Effective Coordination Numbers, ECoN, as well as the Madelung Part of Lattice Energy, MAPLE, have been calculated and are discussed. (author)
Additional details
Additional titles
- Original title (German)
Publishing Information
- Journal Title
- Z. Anorg. Allg. Chem.
- Journal Volume
- 469
- Series
- Z. Anorg. Allg. Chem.
- Journal Page Range
- 149-158
- ISSN
- 0044-2313
INIS
- Country of Publication
- Germany
- Country of Input or Organization
- German Democratic Republic
- INIS RN
- 12594860
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- CESIUM CHLORIDES; COORDINATION NUMBER; DYSPROSIUM CHLORIDES; EXPERIMENTAL DATA; INTERATOMIC DISTANCES; LATTICE PARAMETERS; ORTHORHOMBIC LATTICES; SPACE GROUPS; X-RAY DIFFRACTION
- Descriptors DEC
- ALKALI METAL COMPOUNDS; CESIUM COMPOUNDS; CHLORIDES; CHLORINE COMPOUNDS; COHERENT SCATTERING; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DATA; DIFFRACTION; DISTANCE; DYSPROSIUM COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; INFORMATION; NUMERICAL DATA; RARE EARTH COMPOUNDS; SCATTERING; SYMMETRY GROUPS