Published January 24, 2024 | Version v1
Journal article

Revisiting the heavy-fermion compound YbCdCu4: Kondo temperature and the ground-state degeneracy

  • 1. Department of Physics, Simon Fraser University, Burnaby, British Columbia, Canada V5A 1S6

Description

YbCdCu4 has been characterized as a heavy-fermion Kondo lattice system without long-range magnetic order. Thermodynamic and transport data of this compound have been partially analyzed, and the reported Kondo temperatures TK are highly dependent on samples and estimation methods. In particular, the magnetic susceptibility χ(T) of this compound does not show the maximum corresponding to the Kondo resonance with a large degeneracy of the ground state, partly due to the sample quality. Thus, single crystals of YbCdCu4 are grown to reinvestigate their physical properties by means of magnetization, specific heat, electrical resistivity, Hall resistivity, and thermoelectric power measurements. Unlike earlier studies, we found consistencies regarding the TK160 K measurement estimated from thermodynamic and transport property measurements. The magnetic part of the specific heat Cm displays a broad maximum near 70 K, which follows well with the prediction made by the Coqblin-Schrieffer (C-S) model for whole J=7/2 multiplets involved in the formation of the Kondo state. However, the local maximum in χ(T) does not match well with the C-S model prediction due to the crystalline electric field (CEF) effect, where the TK value is still greater than the overall CEF splittings: TK>ΔCEF. Electrical resistivity and Hall coefficient measurements indicate an extremum near 70 K, while a negative minimum at 130 K is observed in thermoelectric power.

Additional details

Identifiers

DOI
10.1103/PhysRevMaterials.8.013401;
Crossref Funder ID
10.13039/501100001804; 10.13039/501100000038; 10.13039/501100000196;

Publishing Information

Journal Title
Physical Review Materials
Journal Volume
8
Journal Issue
1
Journal Page Range
7 pgs.
ISSN
2475-9953

Optional Information

Copyright
©2024 American Physical Society
Notes
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Funding organization
Canada Research Chairs; Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation