Published July 1999 | Version v1
Journal article Metadata-only

Aziridine interaction with [O(AuPPh3)3BF4. Structure of small gold cluster R-N-(AuPPh3)3BF4 (R CH2CH2(NCH2CH2))

Creators

  • 1. MGU im. M.V. Lomonosova, Moscow (Russian Federation)
  • 2. Inst. Obshchej i Neorganicheskoj Khimii im. N.S. Kurnakova RAN, Moscow (Russian Federation)

Description

Crystal structure of aziridine aurization products with [O(AuPPh3)3BF4 using is determined. All valent angles at ammonium atom of nitrogen CNAu in cation cluster are increased (121(1) deg, 116(1) deg, 119(1) deg), but AuNAu angles are decreased (107.9(6) deg, 93.3(5) deg, 95.1(5) deg) in comparison with ideal tetrahedral angle

Abstract (Russian)

Определена кристаллическая структура продукта аурирования азиридина с помощью [O(AuPPh3)3BF4. В катионном кластере все валентные углы при аммонийном атоме азота CNAu (121(1) град, 116(1) град, 119(1) град) увеличены, а углы AuNAu (107.9(6) град, 93.3(5) град, 95.1(5) град) уменьшены по сравнению с идеальным тетраэдрическим

Additional details

Additional titles

Original title (Russian)
Взаимодейатвие азиридина c [О(AuPPh

Publishing Information

Journal Title
Koordinatsionnaya Khimiya
Journal Volume
25
Journal Issue
7
Journal Page Range
p. 546-550
ISSN
0132-344X
CODEN
KOKHDC

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
31015909
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BOND ANGLE; BOND LENGTHS; BORON COMPOUNDS; CHEMICAL REACTIONS; CRYSTAL STRUCTURE; DENSITY; GOLD COMPLEXES; LATTICE PARAMETERS; ORGANIC NITROGEN COMPOUNDS; ORGANIC PHOSPHORUS COMPOUNDS; SPACE GROUPS
Descriptors DEC
COMPLEXES; DIMENSIONS; LENGTH; ORGANIC COMPOUNDS; PHYSICAL PROPERTIES; SYMMETRY GROUPS; TRANSITION ELEMENT COMPLEXES

Optional Information

Notes
11 refs., 3 tabs.