Published November 1981 | Version v1
Journal article Metadata-only

Ruthenium (4) chloride complex interaction with formic acid and sodium formate in aqueous solutions

Creators

  • 1. Leningradskij Tekhnologicheskij Inst. (USSR)

Description

Using the methods of IR and electron spectroscopy and by measuring molar electric conductivity and magnetic susceptibility (NH4)2RuCl6 interaction with sodium formate and formic acid is studied. It is established that depending on conditions (heating, addition of concentrated HCl, concentration of formic acid) formation of carbonyl-chloride, carbonylformate-chloride or formate-chloride complexes of ruthenium (3) or ruthenium (2) takes place

Additional details

Additional titles

Original title (Russian)
Взаимодействие хлоридных комплексов рутения (4) с муравьиной кислотой и формиатом натрия в водных растворах

Publishing Information

Journal Title
Zh. Prikl. Khim.
Journal Volume
54
Journal Issue
11
Series
Zh. Prikl. Khim.
Journal Page Range
2385-2389
ISSN
0044-4618

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
14763809
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AMMONIUM COMPOUNDS; AQUEOUS SOLUTIONS; CHEMICAL REACTION KINETICS; CHEMICAL REACTIONS; CHLORIDES; ELECTRIC CONDUCTIVITY; ELECTRON SPECTRA; FORMATES; FORMIC ACID; HYDROCHLORIC ACID; INFRARED SPECTRA; MAGNETIC SUSCEPTIBILITY; PH VALUE; RUTHENIUM COMPLEXES; SODIUM COMPOUNDS
Descriptors DEC
ALKALI METAL COMPOUNDS; CARBOXYLIC ACID SALTS; CARBOXYLIC ACIDS; CHLORINE COMPOUNDS; COMPLEXES; DISPERSIONS; ELECTRICAL PROPERTIES; HALIDES; HALOGEN COMPOUNDS; HOMOGENEOUS MIXTURES; HYDROGEN COMPOUNDS; INORGANIC ACIDS; KINETICS; MAGNETIC PROPERTIES; MIXTURES; MONOCARBOXYLIC ACIDS; ORGANIC ACIDS; ORGANIC COMPOUNDS; PHYSICAL PROPERTIES; REACTION KINETICS; SOLUTIONS; SPECTRA; TRANSITION ELEMENT COMPLEXES

Optional Information

Notes
For English translation see the journal Journal of Applied Chemistry of the USSR (USA).