Published July 10, 2017 | Version v1
Journal article Metadata-only

Synthesis, solid-state structure, and bonding analysis of a homoleptic beryllium azide

Creators

  • 1. Faculty of Chemistry and Center for Nanointegration Duisburg-Essen (Cenide), Duisburg-Essen Univ., Essen (Germany)

Description

[Ph4P]2[Be(N3)4] (1) and [PNP]2[Be(N3)4] (2; PNP=Ph3PNPPh3) were synthesized by reacting Be(N3)2 with [Ph4P]N3 and [PNP]N3. Compound 1 represents the first structurally characterized homoleptic beryllium azide. The electronic structure and bonding situation in the tetraazidoberyllate dianion [Be(N3)4]2- were investigated by quantum-chemical calculations (NPA, ELF, LOL). (copyright 2017 Wiley-VCH Verlag GmbH and Co. KGaA, Weinheim)

Availability note (English)

Available from: http://dx.doi.org/10.1002/anie.201703147

Additional details

Identifiers

DOI
10.1002/anie.201703147;

Publishing Information

Journal Title
Angewandte Chemie (International Edition)
Journal Volume
56
Journal Issue
29
Journal Page Range
p. 8559-8563
ISSN
1433-7851
CODEN
ACIEF5

INIS

Country of Publication
Germany
Country of Input or Organization
Germany
INIS RN
48069975
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AZIDES; BERYLLIUM COMPOUNDS; CRYSTAL STRUCTURE; ELECTRONIC STRUCTURE; NMR SPECTRA; SYNTHESIS
Descriptors DEC
ALKALINE EARTH METAL COMPOUNDS; NITROGEN COMPOUNDS; SPECTRA

Optional Information

Notes
With 11 figs., 1 tab., 45 refs.