Published November 1992
| Version v1
Journal article
Kinetics and mechanism of isotopic exchange for methane on group 4 to 8 transition metal borides and silicides
Creators
- 1. L.I. Pisarzhevskii Institute of Physical Chemistry, Kiev (Ukraine)
Description
The isotopic exchange between CH4 and D2 over the metal-like compounds MxLy (M is a transition metal and L is B or Si) has been studied at 973 K to discover how CH4 is activated under conditions corresponding to the oxidative condensation of methane. The principal exchange product is monodeuteromethane, CH3D. The dependence of the specific rate of exchange on the surface area of the catalyst has been established
Additional details
Publishing Information
- Journal Title
- Theoretical and Experimental Chemistry
- Journal Volume
- 28
- Journal Issue
- 3
- Journal Page Range
- p. 170-172.
- ISSN
- 0040-5760
- CODEN
- TEXCAK
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 25024777
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Translation
- Descriptors DEI
- BORIDES; CATALYSTS; CATALYTIC EFFECTS; CHEMICAL ACTIVATION; CHEMICAL REACTION KINETICS; CHROMIUM SILICIDES; COBALT BORIDES; COBALT SILICIDES; DEUTERIUM; HETEROGENEOUS CATALYSIS; IRON BORIDES; ISOTOPIC EXCHANGE; METHANE; MOLYBDENUM SILICIDES; NICKEL BORIDES; SILICIDES; SURFACE AREA; TITANIUM SILICIDES; TUNGSTEN BORIDES; TUNGSTEN SILICIDES
- Descriptors DEC
- ALKANES; BORON COMPOUNDS; CATALYSIS; CHROMIUM COMPOUNDS; COBALT COMPOUNDS; HYDROCARBONS; HYDROGEN ISOTOPES; IRON COMPOUNDS; ISOTOPES; KINETICS; LIGHT NUCLEI; MOLYBDENUM COMPOUNDS; NICKEL COMPOUNDS; NUCLEI; ODD-ODD NUCLEI; ORGANIC COMPOUNDS; REACTION KINETICS; SILICON COMPOUNDS; STABLE ISOTOPES; TITANIUM COMPOUNDS; TRANSITION ELEMENT COMPOUNDS; TUNGSTEN COMPOUNDS
Optional Information
- Notes
- Cover-to-cover Translation of Teoreticheskaia Eksperimental'naia Khimiia (Ukrainian SSR); Translated from Teoreticheskaya i Eksperimental'naya Khimiya; 28: No. 3, 207-210(May-Jun 1992).