Published March 2019 | Version v1
Journal article

Efficient thorium removal by alginate-immobilized Aspergillus niger. Characterization, kinetics, thermodynamic and mechanism analysis

  • 1. Southwest University of Science and Technology, Mianyang, Sichuan (China). Engineering Research Center of Biomass Materials, Ministry of Education
  • 2. Southwest University of Science and Technology, Mianyang, Sichuan (China). School of Life Science and Engineering
  • 3. Southwest University of Science and Technology, Mianyang, Sichuan (China). School of Materials Science and Engineering

Description

In this work, a modified biomass material was successfully prepared by immobilization and inactivation method based on Aspergillus niger, and the obtained environmentally friendly Alginate-immobilized Aspergillus niger microsphere (AAM) exhibited a superior Th(IV) biosorption performance. The sorption kinetics and thermodynamic analysis were studied and showed that the sorption process is spontaneous and endothermic under the experimental conditions. Additionally, the maximum biosorption capacity of AAMs for Th(IV) can be of 303.95 mg g-1 at 313.15 K, which exhibited a superior biosorption capacity than the most reported other biomass materials. The results illustrated the biomaterial had good recyclability through immobilization and inactivation. (author)

Additional details

Publishing Information

Journal Title
Journal of Radioanalytical and Nuclear Chemistry
Journal Volume
319
Journal Issue
3
Journal Page Range
p. 869-880
ISSN
0236-5731
CODEN
JRNCDM

Optional Information

Notes
53 refs.