Published August 1, 1990 | Version v1
Journal article

Nuclear quadrupole moments of 33S and 35S

  • 1. Department of Chemistry, University of Helsinki, Et. Hesperiank. 4, SF-00100 Helsinki (Finland)
  • 2. Theoretical Chemistry, Chemical Centre, University of Lund, P.O. Box 124, S-22100 Lund (Sweden)

Description

The nuclear quadrupole moments of 33S and 35S are studied using numerical multiconfigurational Hartree-Fock (MCHF) calculations on S-(2P3/2). A newly developed finite-element MCHF program allowing very large configuration-interaction expansions is used. The 3p5 valence correlation decreases the electric field gradient with about 12%, but core-valence polarization increases the electric field gradient with about 14% of the Hartree-Fock value. The final values for the nuclear quadrupole moments of 33S and 35S become -0.0678(13) and 0.0471(9) b, respectively

Additional details

Publishing Information

Journal Title
Physical Review, A
Journal Volume
42
Journal Issue
3
Series
Phys. Rev., A.
Journal Page Range
1160-1164
ISSN
0556-2791
CODEN
PLRAA