Published July 1985
| Version v1
Journal article
Production of pernitrite ions under pulse radiolysis of KNO3
- 1. AN SSSR, Moscow. Inst. Organicheskoj Khimii
Description
The process of intramolecular reconstruction of nitrate ion following pulsed irradiation of crystalline KNO3 with accelerated electrons (250 keV, pulse dUration 10 nc, pulse dose rate 8x1011 Gy/s) and with X-rays (dose rate 1.92 Gy/s), is studied. From an analysis of the dependence of the ONO2- concentration in KNO3 on an absorbed dose (0-1.6x105 Gy) for irradiation of a pure and prevously photolized sample, the mechanism of ONO2- production and further transformation is suggested. Production of ONO2- ions is shown to be sensitive to variations in ionizing radiation dose rates. The initial radiation-chemical yield of ONO2- ions was measured to be approximately 1 per 100 eV
Additional details
Additional titles
- Original title (Russian)
- Образование пернитрит-ионов при импульсном радиолизе KNO
Publishing Information
- Journal Title
- Khim. Vys. Ehnerg.
- Journal Volume
- 19
- Journal Issue
- 4
- Series
- Khim. Vys. Ehnerg.
- Journal Page Range
- 347-349
- ISSN
- 0023-1193
- CODEN
- KHVKA
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- USSR
- INIS RN
- 17035120
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- CHEMICAL REACTION KINETICS; CRYSTALS; DOSE RATES; ELECTRONS; G VALUE; KEV RANGE 100-1000; POTASSIUM NITRATES; PULSED IRRADIATION; RADIATION DOSES; RADIOLYSIS; X RADIATION
- Descriptors DEC
- ALKALI METAL COMPOUNDS; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; DECOMPOSITION; ELECTROMAGNETIC RADIATION; ELEMENTARY PARTICLES; ENERGY RANGE; FERMIONS; IONIZING RADIATIONS; IRRADIATION; KEV RANGE; KINETICS; LEPTONS; NITRATES; NITROGEN COMPOUNDS; OXYGEN COMPOUNDS; POTASSIUM COMPOUNDS; RADIATION EFFECTS; RADIATIONS; REACTION KINETICS
Optional Information
- Notes
- For English translation see the journal High Energy Chemistry (USA).