Published 1976
| Version v1
Journal article
The effect of DMSO on adsorption and oxidation of methanol (14C-labelled) on plutonum electrodes
Description
The effect of presence of DMSO in 0.5 M H2SO4 supporting electrolyte on adsorption and anodic oxidation of methanol (14C-labelled) on platinum has been studied by the use of radiochemical and electrochemical methods. The results indicate that DMSO actively interacts with platinum surface. The bulk concentration of DMSO as low as 10-2 M prevents the methanol adsorption and the presence of DMSO has a great influence on the oxidation of methanol chemisorbed species. (S.B.)
Additional details
Publishing Information
- Journal Title
- Rocz. Chem.
- Journal Volume
- 50
- Journal Issue
- 12
- Series
- Rocz. Chem.
- Journal Page Range
- 2113-2119
INIS
- Country of Publication
- Poland
- Country of Input or Organization
- Poland
- INIS RN
- 10447898
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ADSORPTION; ANODES; CARBON 14 COMPOUNDS; CHEMISORPTION; DMSO; ELECTROCHEMISTRY; LAYERS; METHANOL; OXIDATION; PLATINUM; TRACER TECHNIQUES
- Descriptors DEC
- ALCOHOLS; CARBON COMPOUNDS; CHEMICAL REACTIONS; ELECTRODES; ELEMENTS; HYDROXY COMPOUNDS; ISOTOPE APPLICATIONS; METALS; ORGANIC COMPOUNDS; ORGANIC SULFUR COMPOUNDS; PLATINUM METALS; SEPARATION PROCESSES; SULFOXIDES; TRANSITION ELEMENTS