Morphological analysis of ionomers
Description
Anomalous small-angle x-ray scattering (SAXS) investigations were carried out on amorphous and semi-crystalline ionomers (Ni- neutralized sulfonated polystyrene ionomers, polyurethane ionomer). Ionomers with semicrystalline matrices (three-phase materials) were also studied with SAXS (poly(ethylene-co-methacrylic acid) ionomer). Ethylene oxide units were incorporated into the backbone of sulfonated polyurethane ionomers in an attempt to induce aggregate dissociation. Small-angle neutron scattering was used to study the effect of ionic aggregation on ionomer chain dimensions in telechelic and model polyurethane ionomers. Studies have been completed on carboxylated and sulfonated model polyurethane ionomers in order to determine the effect of the pendant ionic group on ionomer structure- property relationships (mechanical properties)
Availability note (English)
MF available from INIS under the Report Number; OSTI as DE92040162; NTIS; INIS; US Govt. Printing Office Dep.
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Additional details
Additional titles
- Subtitle (English)
- Progress report, August 1, 1987--December 31, 1991
Publishing Information
- Imprint Pagination
- 7 p.
- Report number
- DOE/ER/45370--4
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 24010200
- Subject category
- S36: MATERIALS SCIENCE; S36: MATERIALS SCIENCE;
- Resource subtype / Literary indicator
- Progress Report
- Descriptors DEI
- AMORPHOUS STATE; CARBOXYLATION; IONS; MECHANICAL PROPERTIES; MOLECULAR STRUCTURE; MORPHOLOGY; NEUTRON DIFFRACTION; NICKEL; POLYMERS; POLYSTYRENE; POLYURETHANES; PROGRESS REPORT; SMALL ANGLE SCATTERING; SULFONATION; X-RAY DIFFRACTION
- Descriptors DEC
- CHARGED PARTICLES; CHEMICAL REACTIONS; COHERENT SCATTERING; DIFFRACTION; DOCUMENT TYPES; ELEMENTS; METALS; ORGANIC COMPOUNDS; ORGANIC POLYMERS; POLYAMIDES; POLYOLEFINS; POLYVINYLS; SCATTERING; TRANSITION ELEMENTS
Optional Information
- Contract/Grant/Project number
- Contract FG02-88ER45370
- Funding organization
- USDOE, Washington, DC (United States).