Published June 1985 | Version v1
Journal article Metadata-only

Preparation and properties of double oxides ZnSmΛ2OΛ4 and ZnEuΛ2OΛ4 with spinel structure

Creators

  • 1. AN SSSR, Moscow. Inst. Obshchej i Neorganicheskoj Khimii

Description

Compounds ZnSm2O4 and ZnEu2O4 crystallized n spined structure, have been synthesized. It is established, that monophase products are formed at 1100 deg C already in 10 h (intermediate roentgenographic study). Final products have cubic structure of gahnite (spinel) type with unit all parameters 9.228 A for ZnSm2O4 and 9.214 A for ZnEu2O4. Investigation of their optical, electric and magnetic properties is carried out and it is shown, that solid solutions ZnSmsub(2-x)Eusub(x)Osub(4) over the concentration range obey the Vegard law

Additional details

Additional titles

Original title (Russian)
Получение и свойства двойных оксидов ZnSmΛ2OΛ4 и ZnEuΛ2OΛ4 со структурой шпинели

Publishing Information

Journal Title
Zh. Neorg. Khim.
Journal Volume
30
Journal Issue
6
Series
Zh. Neorg. Khim.
Journal Page Range
1595-1597
ISSN
0044-457X
CODEN
ZNOKA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
17015649
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CHEMICAL PREPARATION; CUBIC LATTICES; ELECTRIC CONDUCTIVITY; EUROPIUM OXIDES; INFRARED SPECTRA; LATTICE PARAMETERS; MAGNETIC MOMENTS; SAMARIUM OXIDES; SOLID SOLUTIONS; ZINC OXIDES
Descriptors DEC
CHALCOGENIDES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DISPERSIONS; ELECTRICAL PROPERTIES; EUROPIUM COMPOUNDS; HOMOGENEOUS MIXTURES; MIXTURES; OXIDES; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; RARE EARTH COMPOUNDS; SAMARIUM COMPOUNDS; SOLUTIONS; SPECTRA; SYNTHESIS; ZINC COMPOUNDS

Optional Information

Notes
For English translation see the journal Russian Journal of Inorganic Chemistry (UK).