Published September 2000 | Version v1
Journal article Metadata-only

Crystal structure of Tl4[Re6Se8(CN)6]x1.5H2O

Creators

  • 1. Inst. Khimii Tverdogo Tela i Mekhanokhimii SO RAN, Novosibirsk (Russian Federation)
  • 2. Inst. Neorganicheskoj Khimii SO RAN, Novosibirsk (Russian Federation)

Description

By the method of thallium nitrate and complex K4[Re6Se8(CN)6] aqueous solution diffusion, monocrystals of Tl4[Re6Se8(CN)6]x1.5H2O (1) were grown, their structure being studied by the method of X-ray diffraction analysis. Compound 1 is crystallized in triclinic crystal system with unit cell parameters as follows: a = 12.2855 (3), b = 13.1792 (2), c = 17.3794 (3) A, α = 87.236 (1), β = 76.388 (1), γ = 87.691 (1); sp.gr. P 1, Z = 4, dcalcld. = 6.688 g/cm3. It is ascertained that in the unit cell of 1 there are four crystallographically independent cluster anions [Re6(μ3-Se)8(CN)6]4-

Abstract (Russian)

Методом диффузии водного раствора нитрата таллия и комплекса K4[Re6Se8(CN)6] в силикатном геле выращены монокристаллы Tl4[Re6Se8(CN)6]x1.5H2O (1), строение которого изучено методом рентгеноструктурного анализа. Соединение 1 кристаллизуется в триклинной сингонии с параметрами элементарной ячейки: a = 12,2855 (3), b = 13,1792 (2), c = 17,3794 (3) A, α = 87,236 (1), β = 76,388 (1), γ 87,691 (1); пр.гр. P 1, Z = 4, dвыч = 6,688 г/см3. Установлено, что в элементарной ячейке соединения 1 имеется четыре кристаллографически независимых кластерных аниона [Re6(μ3-Se)8(CN)6]4-

Additional details

Additional titles

Original title (Russian)
Кристаллическая структура Тл

Publishing Information

Journal Title
Zhurnal Strukturnoj Khimii
Journal Volume
41
Journal Issue
5
Journal Page Range
p. 1085-1091
ISSN
0136-7463
CODEN
ZSTKAI

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
32053995
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BOND LENGTHS; CRYSTAL GROWTH; CYANIDES; DENSITY; HYDRATES; LATTICE PARAMETERS; MOLECULAR STRUCTURE; MONOCRYSTALS; RHENIUM COMPLEXES; SELENIDES; THALLIUM COMPOUNDS; TRICLINIC LATTICES; X-RAY DIFFRACTION
Descriptors DEC
CHALCOGENIDES; COHERENT SCATTERING; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; CRYSTALS; DIFFRACTION; DIMENSIONS; LENGTH; PHYSICAL PROPERTIES; SCATTERING; SELENIUM COMPOUNDS; TRANSITION ELEMENT COMPLEXES

Optional Information

Notes
9 refs.; 2 tabs.; 2 figs.