Published October 1988
| Version v1
Journal article
Electromigration of carrier-free radionuclides. 6
- 1. Joint Inst. for Nuclear Research, Dubna (USSR). Lab. of Nuclear Problems
Description
Individual ion mobility of 201Tl(I) uTl+0 = +7.3(3) x 10-4 cm3 s-1 V-1 was observed at 298.1 ± 0.1 K in aqueous solutions of H(K)ClO4, 1.5 · 10-3 ≤ μ ≤ 0.5 and 0.3 ≤ pH ≤ 6.5. Experimental dependences of 201Tl(I) overall ion mobilities on concentrations of ligand anions in solutions of perchlorate background electrolytes have been used to calculate stability constants of neutral thallium complexes Tl I and Tl Br at 298.1 ± 0.1 K and μ = 0.1. They are 115 ± 25 l · mol-1, respectively. (author)
Additional details
Additional titles
- Subtitle (English)
- Iodide and bromide complexes of carrier-free "2"0"1Tl(I) in aqueous solutions
Publishing Information
- Journal Title
- Isotopenpraxis
- Journal Volume
- 24
- Journal Issue
- 10
- Series
- Isotopenpraxis.
- Journal Page Range
- 383-386
- ISSN
- 0021-1915
- CODEN
- IPRXA
INIS
- Country of Publication
- Germany
- Country of Input or Organization
- German Democratic Republic
- INIS RN
- 19103889
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Is Lead record
- Yes
- Descriptors DEI
- AQUEOUS SOLUTIONS; CARRIER-FREE ISOTOPES; CATIONS; ELECTROPHORESIS; ION MOBILITY; PERCHLORATES; PH VALUE; STABILITY; THALLIUM BROMIDES; THALLIUM COMPLEXES; THALLIUM COMPOUNDS; THALLIUM IODIDES; THALLIUM 201
- Descriptors DEC
- BETA DECAY RADIOISOTOPES; BROMIDES; BROMINE COMPOUNDS; CHARGED PARTICLES; CHLORINE COMPOUNDS; COMPLEXES; DAYS LIVING RADIOISOTOPES; DISPERSIONS; ELECTRON CAPTURE RADIOISOTOPES; HALIDES; HALOGEN COMPOUNDS; HEAVY NUCLEI; HOMOGENEOUS MIXTURES; IODIDES; IODINE COMPOUNDS; IONS; ISOTOPES; MIXTURES; MOBILITY; NUCLEI; ODD-EVEN NUCLEI; OXYGEN COMPOUNDS; PARTICLE MOBILITY; RADIOISOTOPES; SOLUTIONS; THALLIUM HALIDES; THALLIUM ISOTOPES